Fractions are presented in Figure five [43,469].Processes 2021, 9,course of hydrothermal experiments. The LY294002 Autophagy content material of monoaromatic steroids is substantially larger inside the composition of oil in the Domanic rocks of the Berezovskaya area in comparison on the oil from carbonate rocks with the Zelenogorskaya area: three.46 vs. 19.sixteen and five.75 vs. 10.74 , correspondingly (Table 3). The articles of such hydrocarbons right after hydrocarbon treatment of rocks decreases from five.75 to four.99 during the saturates fraction of twelve of twenty the oil extracted through the Zelenogorskaya rock sample. Oppositely, the outlined hydrocarbons significantly boost (from 10.74 to 18.18 ) during the saturates fraction of oil extracted through the Berezovskaya rock sample.(b)Processes 2021, 9, x FOR PEER REVIEW13 of(c)(d)Figure 4. Mass-fragmentogram at m/z 133 for saturated fractions of rock samples from your Zelenogorskaya and Bere4. Mass-fragmentogram at m/z 133 for saturated fractions of rock samples from the Zelenogorskaya and Berebefore (a,c) and immediately after (b,d) the experiments. C12 22 –the number of carbon atoms in aryl isoprenoids. zovskaya GNF6702 Parasite regions ahead of (a,c) and after (b,d) the experiments. C12 22–the quantity of carbon atoms in aryl isoprenoids.Hydrocarbon composition of aromatic fractions of shale oil. The relative content of various hydrocarbon groups taking into consideration trimethyl benzene, naphthalene, phenanthrene, benzthiophene, dibenzothiophene (DBT) in aromatic fractions of shale oil from Zelenogorskaya and Berezovskaya rock samples are presented in Table five, along with the TIC of aromatic fractions are presented in Figure five [43,469].Table 5. Relative content material of different style of compounds in aromatic fractions of shale oil just before and following the hydrothermal experiments.Processes 2021, 9, x Processes 2021, 9, 1798FOR PEER REVIEW14 of 21 13 of(b)(c)(d)Figure five. TIC of aromatic fractions of shale oil from your rock samples of Zelenogorskaya and Berezovskaya regions just before (a,c) and just after (b,d) hydrothermal experiments. N–naphthalene, P–phenanthrene, DBT–dibenzothiophene and BT– benzothiophene, n–number of carbon atoms in alkyl substitutes of Cn .Processes 2021, 9,14 ofTable five. Relative content of various form of compounds in aromatic fractions of shale oil just before and just after the hydrothermal experiments. Zelenogorskaya Spot Compounds Alkyltrimethylbenzenes (m/z 133 134) Just before Practical experience 9.08 18.01 6.86 Immediately after Practical experience 2.73 23.16 14.34 Berezovskaya Spot Before Expertise one.40 25.14 six.24 Right after Expertise one.15 ofProcesses 2021, 9, x FOR PEER REVIEWNaphthalenes (m/z 128 142 156 170) Phenanthrenes (m/z 178 192 206)27.86 eleven.Benzothiophenes (m/z 147 161 175) 56.64 42.71 56.ten 38.75 Figure five. TIC of aromatic fractions of shale oil through the rock samples of Zelenogorskaya and Berezovskaya parts prior to Dibenzothiophenes (m/z 184 198 experiments. N–naphthalene, P–phenanthrene, DBT–dibenzothiophene and BT– 9.42 17.07 eleven.12 20.42 (a,c) and following (b,d) hydrothermal 212) benzothiophene, n–number of carbon atoms in alkyl substitutes of Cn.The concentrations of aromatic sulfur organic compounds, benzothiophene (56.64 as well as the concentrations of aromatic sulfur natural compounds, benzothiophene (56.64 56.10 ), are high inside the composition of aromatic fractions of shale oil, independent from and 56.ten ), are higher in the composition of aromatic fractions of shale oil, independent the rock sort. Immediately after the hydrothermal treatment of rock samples, the material of such from the rock form. Just after the hydrother.